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Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single dias...

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Detalles Bibliográficos
Autores principales: Roy, Sudipta Raha, Eijsberg, Hendrik, Bruffaerts, Jeffrey, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365058/
https://www.ncbi.nlm.nih.gov/pubmed/28451177
http://dx.doi.org/10.1039/c6sc02617f