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Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane
The structure and dynamics of enigmatic hexa(3,5-di-tert-butylphenyl)ethane was characterized via NMR spectroscopy for the first time. Our variable temperature NMR analysis demonstrates an enthalpy–entropy compensation that results in a vanishingly low dissociation energy (ΔG298d = –1.60(6) kcal mol...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365070/ https://www.ncbi.nlm.nih.gov/pubmed/28451185 http://dx.doi.org/10.1039/c6sc02727j |