Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes

Early transition metals (TMs), such as titanium, generally resist undergoing reductive elimination to form C–X bonds due to their weak electronegativity. By analyzing the mechanism of the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes, the present study revealed that titanium is...

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Detalles Bibliográficos
Autores principales: Guo, Jiandong, Deng, Xi, Song, Chunyu, Lu, Yu, Qu, Shuanglin, Dang, Yanfeng, Wang, Zhi-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369339/
https://www.ncbi.nlm.nih.gov/pubmed/28451348
http://dx.doi.org/10.1039/c6sc04456e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369339/
https://www.ncbi.nlm.nih.gov/pubmed/28451348
http://dx.doi.org/10.1039/c6sc04456e

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