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Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes
Early transition metals (TMs), such as titanium, generally resist undergoing reductive elimination to form C–X bonds due to their weak electronegativity. By analyzing the mechanism of the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes, the present study revealed that titanium is...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369339/ https://www.ncbi.nlm.nih.gov/pubmed/28451348 http://dx.doi.org/10.1039/c6sc04456e |