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Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
A general efficient regioselective cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds of aliphatic amides was demonstrated using atmospheric (1–2 atm) carbon monoxide as a C1 source. This straightforward approach provides access to α-spiral succinimide regioselectively in a good yield. C...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369400/ https://www.ncbi.nlm.nih.gov/pubmed/28451350 http://dx.doi.org/10.1039/c6sc05026c |