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Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds

A general efficient regioselective cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds of aliphatic amides was demonstrated using atmospheric (1–2 atm) carbon monoxide as a C1 source. This straightforward approach provides access to α-spiral succinimide regioselectively in a good yield. C...

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Detalles Bibliográficos
Autores principales:	Barsu, Nagaraju, Bolli, Shyam Kumar, Sundararaju, Basker
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369400/ https://www.ncbi.nlm.nih.gov/pubmed/28451350 http://dx.doi.org/10.1039/c6sc05026c

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