Geminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide

Cyclopropylacetylene reacts with two molar equivalents of Piers' borane [HB(C(6)F(5))(2)] under mild conditions by an addition/rearrangement sequence with cyclopropyl ring opening to give a mixture of two α-B(C(6)F(5))(2) substituted tetrahydroboroles. This compound forms an active frustrated L...

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Detalles Bibliográficos
Autores principales: Liu, Yun-Lin, Kehr, Gerald, Daniliuc, Constantin G., Erker, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369401/
https://www.ncbi.nlm.nih.gov/pubmed/28451249
http://dx.doi.org/10.1039/c6sc03468c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369401/
https://www.ncbi.nlm.nih.gov/pubmed/28451249
http://dx.doi.org/10.1039/c6sc03468c

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