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Geminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide
Cyclopropylacetylene reacts with two molar equivalents of Piers' borane [HB(C(6)F(5))(2)] under mild conditions by an addition/rearrangement sequence with cyclopropyl ring opening to give a mixture of two α-B(C(6)F(5))(2) substituted tetrahydroboroles. This compound forms an active frustrated L...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369401/ https://www.ncbi.nlm.nih.gov/pubmed/28451249 http://dx.doi.org/10.1039/c6sc03468c |