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Cu(0), O(2) and mechanical forces: a saving combination for efficient production of Cu–NHC complexes

Mechanical forces induced by ball-milling agitation enabled the highly efficient and widely applicable synthesis of Cu–carbene complexes from N,N-diaryl-imidazolium salts and metallic copper. The required amount of gaseous dioxygen and insoluble copper could be reduced down to stoichiometric quantit...

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Detalles Bibliográficos
Autores principales: Beillard, Audrey, Métro, Thomas-Xavier, Bantreil, Xavier, Martinez, Jean, Lamaty, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5369405/
https://www.ncbi.nlm.nih.gov/pubmed/28451247
http://dx.doi.org/10.1039/c6sc03182j