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Anisotropic Charge Distribution and Anisotropic van der Waals Radius Leading to Intriguing Anisotropic Noncovalent Interactions

Although group (IV–VII) nonmetallic elements do not favor interacting with anionic species, there are counterexamples including the halogen bond. Such binding is known to be related to the charge deficiency because of the adjacent atom's electron withdrawing effect, which creates σ/π-holes at t...

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Detalles Bibliográficos
Autores principales: Kim, Hahn, Van Dung Doan, Cho, Woo Jong, Madhav, Miriyala Vijay, Kim, Kwang S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5376054/
https://www.ncbi.nlm.nih.gov/pubmed/25059645
http://dx.doi.org/10.1038/srep05826