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Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

Although great success has been achieved in asymmetric fluoroalkylation reactions via nucleophilic or electrophilic processes, the development of asymmetric radical versions of this type of reactions remains a formidable challenge because of the involvement of highly reactive radical species. Here w...

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Detalles Bibliográficos
Autores principales: Lin, Jin-Shun, Wang, Fu-Li, Dong, Xiao-Yang, He, Wei-Wei, Yuan, Yue, Chen, Su, Liu, Xin-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5376653/
https://www.ncbi.nlm.nih.gov/pubmed/28332576
http://dx.doi.org/10.1038/ncomms14841