Selective uni- and bidirectional homologation of diborylmethane

Diborylmethane can be homologated uni- and bidirectionally by using enantiomerically pure lithium-stabilized carbenoids to give 1,2- and 1,3-bis(boronic esters), respectively, in good yield and with excellent levels of enantio- and diastereoselectivity. The high sensitivity of the transformation to...

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Detalles Bibliográficos
Autores principales: Blair, Daniel J., Tanini, Damiano, Bateman, Joseph M., Scott, Helen K., Myers, Eddie L., Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5376717/
https://www.ncbi.nlm.nih.gov/pubmed/28451355
http://dx.doi.org/10.1039/c6sc05338f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5376717/
https://www.ncbi.nlm.nih.gov/pubmed/28451355
http://dx.doi.org/10.1039/c6sc05338f

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