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Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen

The ability of Au catalysts to effect the challenging task of utilizing molecular oxygen for the selective epoxidation of cyclooctene is fascinating. Although supported nanometre-size Au particles are poorly active, here we show that solubilized atomic Au clusters, present in ng ml(−1) concentration...

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Detalles Bibliográficos
Autores principales: Qian, Linping, Wang, Zhen, Beletskiy, Evgeny V., Liu, Jingyue, dos Santos, Haroldo J., Li, Tiehu, Rangel, Maria do C., Kung, Mayfair C., Kung, Harold H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5379066/
https://www.ncbi.nlm.nih.gov/pubmed/28348389
http://dx.doi.org/10.1038/ncomms14881