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Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

Intensive efforts for the transformation of dinitrogen using transition metal–dinitrogen complexes as catalysts under mild reaction conditions have been made. However, limited systems have succeeded in the catalytic formation of ammonia. Here we show that newly designed and prepared dinitrogen-bridg...

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Detalles Bibliográficos
Autores principales: Eizawa, Aya, Arashiba, Kazuya, Tanaka, Hiromasa, Kuriyama, Shogo, Matsuo, Yuki, Nakajima, Kazunari, Yoshizawa, Kazunari, Nishibayashi, Yoshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382288/
https://www.ncbi.nlm.nih.gov/pubmed/28374835
http://dx.doi.org/10.1038/ncomms14874