Cargando…
Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
Intensive efforts for the transformation of dinitrogen using transition metal–dinitrogen complexes as catalysts under mild reaction conditions have been made. However, limited systems have succeeded in the catalytic formation of ammonia. Here we show that newly designed and prepared dinitrogen-bridg...
Autores principales: | Eizawa, Aya, Arashiba, Kazuya, Tanaka, Hiromasa, Kuriyama, Shogo, Matsuo, Yuki, Nakajima, Kazunari, Yoshizawa, Kazunari, Nishibayashi, Yoshiaki |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382288/ https://www.ncbi.nlm.nih.gov/pubmed/28374835 http://dx.doi.org/10.1038/ncomms14874 |
Ejemplares similares
-
Unique behaviour of dinitrogen-bridged
dimolybdenum complexes bearing pincer ligand towards catalytic formation of
ammonia
por: Tanaka, Hiromasa, et al.
Publicado: (2014) -
Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site
por: Kuriyama, Shogo, et al.
Publicado: (2015) -
Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
por: Kuriyama, Shogo, et al.
Publicado: (2016) -
Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand
por: Itabashi, Takayuki, et al.
Publicado: (2022) -
Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation
por: Kuriyama, Shogo, et al.
Publicado: (2022)