Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate

The title compound, C(22)H(25)NO(5), was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H⋯O and reinforcing C—H⋯O hydrogen b...

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Detalles Bibliográficos
Autores principales: Manchado, Alejandro, Salgado, Mateo M., Vicente, Álvaro, Díez, David, Sanz, Francisca, Garrido, Narciso M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382608/
https://www.ncbi.nlm.nih.gov/pubmed/28435707
http://dx.doi.org/10.1107/S2056989017003607
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author Manchado, Alejandro
Salgado, Mateo M.
Vicente, Álvaro
Díez, David
Sanz, Francisca
Garrido, Narciso M.
author_facet Manchado, Alejandro
Salgado, Mateo M.
Vicente, Álvaro
Díez, David
Sanz, Francisca
Garrido, Narciso M.
author_sort Manchado, Alejandro
collection PubMed
description The title compound, C(22)H(25)NO(5), was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H⋯O and reinforcing C—H⋯O hydrogen bonds link the mol­ecules into infinite [010] chains. Further C—H⋯O hydrogen bonds cross-link the chains in the c-axis direction.
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spelling pubmed-53826082017-04-21 Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate Manchado, Alejandro Salgado, Mateo M. Vicente, Álvaro Díez, David Sanz, Francisca Garrido, Narciso M. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(22)H(25)NO(5), was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H⋯O and reinforcing C—H⋯O hydrogen bonds link the mol­ecules into infinite [010] chains. Further C—H⋯O hydrogen bonds cross-link the chains in the c-axis direction. International Union of Crystallography 2017-03-14 /pmc/articles/PMC5382608/ /pubmed/28435707 http://dx.doi.org/10.1107/S2056989017003607 Text en © Manchado et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Manchado, Alejandro
Salgado, Mateo M.
Vicente, Álvaro
Díez, David
Sanz, Francisca
Garrido, Narciso M.
Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title_full Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title_fullStr Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title_full_unstemmed Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title_short Crystal structure of methyl (4R)-4-(4-meth­oxy­benzo­yl)-4-{[(1R)-1-phenyl­eth­yl]carbamo­yl}butano­ate
title_sort crystal structure of methyl (4r)-4-(4-meth­oxy­benzo­yl)-4-{[(1r)-1-phenyl­eth­yl]carbamo­yl}butano­ate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382608/
https://www.ncbi.nlm.nih.gov/pubmed/28435707
http://dx.doi.org/10.1107/S2056989017003607
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