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Easy access to nucleophilic boron through diborane to magnesium boryl metathesis

Organoboranes are some of the most synthetically valuable and widely used intermediates in organic and pharmaceutical chemistry. Their synthesis, however, is limited by the behaviour of common boron starting materials as archetypal Lewis acids such that common routes to organoboranes rely on the rea...

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Detalles Bibliográficos
Autores principales: Pécharman, Anne-Frédérique, Colebatch, Annie L., Hill, Michael S., McMullin, Claire L., Mahon, Mary F., Weetman, Catherine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5385571/
https://www.ncbi.nlm.nih.gov/pubmed/28387308
http://dx.doi.org/10.1038/ncomms15022