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Catalytic Asymmetric Formal Total Synthesis of (−)-Triptophenolide and (+)-Triptolide
ABSTRACT: Catalytic asymmetric formal synthesis of (−)-Triptophenolide and (+)-Triptolide have been achieved. Key reaction involves Palladium catalyzed asymmetric conjugate addition of aryl boronic acid to 3-methyl cyclohexe-1-none to form quaternary carbon. Claisen rearrangement and subsequent aldo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Berlin Heidelberg
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5385656/ https://www.ncbi.nlm.nih.gov/pubmed/27095015 http://dx.doi.org/10.1007/s13659-016-0100-z |