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Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy
[Image: see text] Catalysis of H(2) production and oxidation reactions is critical in renewable energy systems based around H(2) as a clean fuel, but the present reliance on platinum-based catalysts is not sustainable. In nature, H(2) is oxidized at minimal overpotential and high turnover frequencie...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5387674/ https://www.ncbi.nlm.nih.gov/pubmed/28413691 http://dx.doi.org/10.1021/acscatal.6b03182 |