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Unpredictable cycloisomerization of 1,11-dien-6-ynes by a common cobalt catalyst

1,11-Dien-6-ynes undergo cycloisomerization in the presence of the cobalt catalytic system CoBr(2)/phosphine ligand/Zn/ZnI(2) giving cyclohexene, diene or cyclopropane structures depending on the type of the phosphine ligand. This unpredictable behaviour suggests that, although the availability of t...

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Detalles Bibliográficos
Autores principales: Suleymanov, Abdusalom A, Vasilyev, Dmitry V, Novikov, Valentin V, Nelyubina, Yulia V, Perekalin, Dmitry S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5389203/
https://www.ncbi.nlm.nih.gov/pubmed/28487757
http://dx.doi.org/10.3762/bjoc.13.62