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Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Polysilane/SiO(2)‐Supported Palladium Catalyst under Continuous‐Flow Conditions

Hydrogenation of nitriles to primary amines with heterogeneous catalysts under liquid‐phase continuous‐flow conditions is described. Newly developed polysilane/SiO(2)‐supported Pd was found to be an effective catalyst and various nitriles were converted into primary amine salts in almost quantitativ...

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Detalles Bibliográficos
Autores principales: Saito, Yuki, Ishitani, Haruro, Ueno, Masaharu, Kobayashi, Shū
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390790/
https://www.ncbi.nlm.nih.gov/pubmed/28413753
http://dx.doi.org/10.1002/open.201600166