Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5‐Aminothiazoles

Chemical or electrochemical one‐electron oxidation of 5‐N‐arylaminothiazoles was found to afford stable radical cations. For chemical oxidation, 1 equivalent of [(4‐BrC(6)H(4))(3)N][SbCl(6)] (Magic Blue, MB) was added to CH(2)Cl(2) solutions of the thiazoles, and the thus‐obtained radicals showed li...

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Detalles Bibliográficos
Autores principales: Yamaguchi, Kirara, Murai, Toshiaki, Kutsumizu, Shoichi, Miwa, Yohei, Ebihara, Masahiro, Guo, Jing‐Dong, Tokitoh, Norihiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390811/
https://www.ncbi.nlm.nih.gov/pubmed/28413765
http://dx.doi.org/10.1002/open.201700016

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390811/
https://www.ncbi.nlm.nih.gov/pubmed/28413765
http://dx.doi.org/10.1002/open.201700016

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