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Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5‐Aminothiazoles
Chemical or electrochemical one‐electron oxidation of 5‐N‐arylaminothiazoles was found to afford stable radical cations. For chemical oxidation, 1 equivalent of [(4‐BrC(6)H(4))(3)N][SbCl(6)] (Magic Blue, MB) was added to CH(2)Cl(2) solutions of the thiazoles, and the thus‐obtained radicals showed li...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390811/ https://www.ncbi.nlm.nih.gov/pubmed/28413765 http://dx.doi.org/10.1002/open.201700016 |