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Observation of a re-entrant phase transition in the molecular complex tris(μ(2)-3,5-diisopropyl-1,2,4-triazolato-κ(2) N (1):N (2))trigold(I) under high pressure
We report a molecular crystal that exhibits four successive phase transitions under hydrostatic pressure, driven by aurophilic interactions, with the ground-state structure re-emerging at high pressure. The effect of pressure on two polytypes of tris(μ(2)-3,5-diisopropyl-1,2,4-triazolato-κ(2) N (1...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5391858/ https://www.ncbi.nlm.nih.gov/pubmed/28461897 http://dx.doi.org/10.1107/S2052252516013129 |