Observation of a re-entrant phase transition in the molecular complex tris(μ(2)-3,5-diiso­propyl-1,2,4-triazolato-κ(2) N (1):N (2))trigold(I) under high pressure

We report a molecular crystal that exhibits four successive phase transitions under hydro­static pressure, driven by aurophilic interactions, with the ground-state structure re-emerging at high pressure. The effect of pressure on two polytypes of tris(μ(2)-3,5-diiso­propyl-1,2,4-triazolato-κ(2) N (1...

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Detalles Bibliográficos
Autores principales: Woodall, Christopher H., Christensen, Jeppe, Skelton, Jonathan M., Hatcher, Lauren E., Parlett, Andrew, Raithby, Paul R., Walsh, Aron, Parker, Stephen C., Beavers, Christine M., Teat, Simon J., Intissar, Mourad, Reber, Christian, Allan, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5391858/
https://www.ncbi.nlm.nih.gov/pubmed/28461897
http://dx.doi.org/10.1107/S2052252516013129

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