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Self‐Templating and In Situ Assembly of a Cubic Cluster‐of‐Clusters Architecture Based on a {Mo(24)Fe(12)} Inorganic Macrocycle

Engineering self‐templating inorganic architectures is critical for the development of bottom‐up approaches to nanoscience, but systems with a hierarchy of templates are elusive. Herein we describe that the cluster‐anion‐templated (CAT) assembly of a {CAT}⊂{Mo(24)Fe(12)} macrocycle forms a giant ca....

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Detalles Bibliográficos
Autores principales: Xuan, Weimin, Surman, Andrew J., Zheng, Qi, Long, De‐Liang, Cronin, Leroy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396355/
https://www.ncbi.nlm.nih.gov/pubmed/27358195
http://dx.doi.org/10.1002/anie.201603298