Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation

The one-step conversion of aliphatic carboxylic acids to the corresponding nitriles has been accomplished via the merger of visible light mediated photoredox and cyanobenziodoxolones (CBX) reagents. The reaction proceeded in high yields with natural and non-natural α-amino and α-oxy acids, affording...

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Detalles Bibliográficos
Autores principales: Le Vaillant, Franck, Wodrich, Matthew D., Waser, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396527/
https://www.ncbi.nlm.nih.gov/pubmed/28451301
http://dx.doi.org/10.1039/c6sc04907a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396527/
https://www.ncbi.nlm.nih.gov/pubmed/28451301
http://dx.doi.org/10.1039/c6sc04907a

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