Substitution of fluorine in M[C(6)F(5)BF(3)] with organolithium compounds: distinctions between O- and N-nucleophiles

Borates M[C(6)F(5)BF(3)] (M = K, Li, Bu(4)N) react with organolithium compounds, RLi (R = Me, Bu, Ph), in 1,2-dimethoxyethane or diglyme to give M[4-RC(6)F(4)BF(3)] and M[2-RC(6)F(4)BF(3)]. When R is Me or Bu, the nucleophilic substitution of the fluorine atom at the para position to boron is the pr...

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Detalles Bibliográficos
Autores principales: Shabalin, Anton Yu, Adonin, Nicolay Yu, Bardin, Vadim V
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5405681/
https://www.ncbi.nlm.nih.gov/pubmed/28503205
http://dx.doi.org/10.3762/bjoc.13.69

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5405681/
https://www.ncbi.nlm.nih.gov/pubmed/28503205
http://dx.doi.org/10.3762/bjoc.13.69

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