Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diamine Precursor into a Highly Active Aerobic Oxidation Catalyst

[Image: see text] A homogeneous Cu-based catalyst system consisting of [Cu(MeCN)(4)]PF(6), N,N′-di-tert-butylethylenediamine (DBED), and p-(N,N-dimethylamino)pyridine (DMAP) mediates efficient aerobic oxidation of alcohols. Mechanistic study of this reaction shows that the catalyst undergoes an in s...

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Detalles Bibliográficos
Autores principales: McCann, Scott D., Lumb, Jean-Philip, Arndtsen, Bruce A., Stahl, Shannon S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5408333/
https://www.ncbi.nlm.nih.gov/pubmed/28470049
http://dx.doi.org/10.1021/acscentsci.7b00022

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5408333/
https://www.ncbi.nlm.nih.gov/pubmed/28470049
http://dx.doi.org/10.1021/acscentsci.7b00022

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