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Controlled Interconversion of a Dinuclear Au Species Supported by a Redox‐Active Bridging PNP Ligand Facilitates Ligand‐to‐Gold Electron Transfer

Redox non‐innocent ligands have recently emerged as interesting tools to obtain new reactivity with a wide variety of metals. However, gold has almost been neglected in this respect. Here, we report mechanistic investigations related to a rare example of ligand‐based redox chemistry in the coordinat...

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Detalles Bibliográficos
Autores principales: Vreeken, Vincent, Siegler, Maxime A., van der Vlugt, Jarl Ivar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5413818/
https://www.ncbi.nlm.nih.gov/pubmed/28248000
http://dx.doi.org/10.1002/chem.201700360