Diastereoselective Radical‐Type Cyclopropanation of Electron‐Deficient Alkenes Mediated by the Highly Active Cobalt(II) Tetramethyltetraaza[14]annulene Catalyst

A new protocol for the catalytic synthesis of cyclopropanes using electron‐deficient alkenes is presented, which is catalysed by a series of affordable, easy to synthesise and highly active substituted cobalt(II) tetraaza[14]annulenes. These catalysts are compatible with the use of sodium tosylhydra...

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Detalles Bibliográficos
Autores principales: Chirila, Andrei, Gopal Das, Braja, Paul, Nanda D., de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5413858/
https://www.ncbi.nlm.nih.gov/pubmed/28529668
http://dx.doi.org/10.1002/cctc.201601568

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5413858/
https://www.ncbi.nlm.nih.gov/pubmed/28529668
http://dx.doi.org/10.1002/cctc.201601568

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