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Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts
The first heterobimetallic sandwich-type aggregate formed by bowl-shaped corannulene trianion-radicals, C(20)H(10)˙(3–), has been synthesized using mixed-metal reduction of C(20)H(10). The product was crystallographically characterized to reveal the self-assembly of [Cs(+)//(C(20)H(10) (3–))/4K(+)/(...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5413885/ https://www.ncbi.nlm.nih.gov/pubmed/28507689 http://dx.doi.org/10.1039/c6sc05370j |