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Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh

The manuscript reports the synthesis, characterization, and analysis of electronic structure in a series of complexes of small perfluorocarbon ligands with the (PNP)Rh fragment (where PNP is a diarylamido/bis(phosphine) pincer ligand). Reactions of (PNP)Rh(TBE) as the source of (PNP)Rh with CHF(3) a...

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Detalles Bibliográficos
Autores principales: Pell, Christopher J., Zhu, Yanjun, Huacuja, Rafael, Herbert, David E., Hughes, Russell P., Ozerov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5414389/
https://www.ncbi.nlm.nih.gov/pubmed/28507693
http://dx.doi.org/10.1039/c6sc05391b