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Redox non-innocence permits catalytic nitrene carbonylation by (dadi)Ti[double bond, length as m-dash]NAd (Ad = adamantyl)
Application of the diamide, diimine {–CH[double bond, length as m-dash]N(1,2-C(6)H(4))N(2,6-(i)Pr(2)-C(6)H(3))}(2) ( m ) ((dadi)( m )) ligand to titanium provided adducts (dadi)TiL( x ) (1-L( x ); L( x ) = THF, PMe(2)Ph, (CNMe)(2)), which possess the redox formulation [(dadi)(4–)]Ti(iv)L( x ), and 2...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5417046/ https://www.ncbi.nlm.nih.gov/pubmed/28507712 http://dx.doi.org/10.1039/c6sc05610e |