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Redox non-innocence permits catalytic nitrene carbonylation by (dadi)Ti[double bond, length as m-dash]NAd (Ad = adamantyl)

Application of the diamide, diimine {–CH[double bond, length as m-dash]N(1,2-C(6)H(4))N(2,6-(i)Pr(2)-C(6)H(3))}(2) ( m ) ((dadi)( m )) ligand to titanium provided adducts (dadi)TiL( x ) (1-L( x ); L( x ) = THF, PMe(2)Ph, (CNMe)(2)), which possess the redox formulation [(dadi)(4–)]Ti(iv)L( x ), and 2...

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Detalles Bibliográficos
Autores principales: Heins, Spencer P., Wolczanski, Peter T., Cundari, Thomas R., MacMillan, Samantha N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5417046/
https://www.ncbi.nlm.nih.gov/pubmed/28507712
http://dx.doi.org/10.1039/c6sc05610e