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Synthesis and crystallographic characterization of a mononuclear cobalt(III) complex possessing both thiol­ate and thio­ether donors: reactivity of an thiol­ate-bridged penta­nuclear Co(2)Ag(3) complex with iodo­methane

Treatment of an S-bridged penta­nuclear Ag(I) (3)Co(III) (2) complex, [Ag(3){Co(L)}(2)](3+) [L (3–) = N(CH(2)NHCH(2)CH(2)S(−))(3)], in which two tris­(thiol­ate)-type mononuclear Co(III) units ([Co(L)]) are bridged by three Ag(I) ions through S atoms, with iodo­methane (CH(3)I) gave a new Co(III) mo...

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Detalles Bibliográficos
Autores principales: Fukuda, Yosuke, Yoshinari, Nobuto, Konno, Takumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418782/
https://www.ncbi.nlm.nih.gov/pubmed/28529774
http://dx.doi.org/10.1107/S2056989017005229