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Synthesis and crystallographic characterization of a mononuclear cobalt(III) complex possessing both thiolate and thioether donors: reactivity of an thiolate-bridged pentanuclear Co(2)Ag(3) complex with iodomethane
Treatment of an S-bridged pentanuclear Ag(I) (3)Co(III) (2) complex, [Ag(3){Co(L)}(2)](3+) [L (3–) = N(CH(2)NHCH(2)CH(2)S(−))(3)], in which two tris(thiolate)-type mononuclear Co(III) units ([Co(L)]) are bridged by three Ag(I) ions through S atoms, with iodomethane (CH(3)I) gave a new Co(III) mo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418782/ https://www.ncbi.nlm.nih.gov/pubmed/28529774 http://dx.doi.org/10.1107/S2056989017005229 |