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Stereoselectivity of Conformationally Restricted Glucosazide Donors

[Image: see text] Glycosylations of 4,6-tethered glucosazide donors with a panel of model acceptors revealed the effect of acceptor nucleophilicity on the stereoselectivity of these donors. The differences in reactivity among the donors were evaluated in competitive glycosylation reactions, and thei...

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Detalles Bibliográficos
Autores principales: van der Vorm, Stefan, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5423080/
https://www.ncbi.nlm.nih.gov/pubmed/28401764
http://dx.doi.org/10.1021/acs.joc.7b00470