Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides

[Image: see text] An electrophilic, imide-based, visible-light-promoted photoredox/Ni-catalyzed cross-coupling reaction for the synthesis of aliphatic ketones has been developed. This protocol proceeds through N–C(O) bond activation, made possible through the lower activation energy for metal insert...

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Detalles Bibliográficos
Autores principales: Amani, Javad, Alam, Rauful, Badir, Shorouk, Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5423445/
https://www.ncbi.nlm.nih.gov/pubmed/28445061
http://dx.doi.org/10.1021/acs.orglett.7b00989

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5423445/
https://www.ncbi.nlm.nih.gov/pubmed/28445061
http://dx.doi.org/10.1021/acs.orglett.7b00989

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