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Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins

Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products, pharmaceuticals and manmade materials. Converting the normally highly stable aliphatic amides into olefins directly is a challenging task. Here we show...

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Detalles Bibliográficos
Autores principales: Hu, Jiefeng, Wang, Minyan, Pu, Xinghui, Shi, Zhuangzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424121/
https://www.ncbi.nlm.nih.gov/pubmed/28474671
http://dx.doi.org/10.1038/ncomms14993