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Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins
Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products, pharmaceuticals and manmade materials. Converting the normally highly stable aliphatic amides into olefins directly is a challenging task. Here we show...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424121/ https://www.ncbi.nlm.nih.gov/pubmed/28474671 http://dx.doi.org/10.1038/ncomms14993 |