Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions

[Image: see text] A highly stereoselective gold(I)-catalyzed cis-vinylcyclopropanation of alkenes has been developed. Allylic gold carbenes, generated via a retro-Buchner reaction of 7-alkenyl-1,3,5-cycloheptatrienes, react with alkenes to form vinylcyclopropanes. The gold(I)-catalyzed retro-Buchner...

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Detalles Bibliográficos
Autores principales: Herlé, Bart, Holstein, Philipp M., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424441/
https://www.ncbi.nlm.nih.gov/pubmed/28503355
http://dx.doi.org/10.1021/acscatal.7b00737

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424441/
https://www.ncbi.nlm.nih.gov/pubmed/28503355
http://dx.doi.org/10.1021/acscatal.7b00737

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