Selecting reactions and reactants using a switchable rotaxane organocatalyst with two different active sites

The activation mode of a rotaxane-based organocatalyst with both secondary amine and squaramide catalytic units can be switched with acid or base. The macrocycle blocks whichever of the catalytic sites it is positioned over. The switchable rotaxane catalyst generates different products from a mixtur...

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Detalles Bibliográficos
Autores principales: Beswick, Jack, Blanco, Victor, De Bo, Guillaume, Leigh, David A., Lewandowska, Urszula, Lewandowski, Bartosz, Mishiro, Kenji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424444/
https://www.ncbi.nlm.nih.gov/pubmed/28553462
http://dx.doi.org/10.1039/c4sc03279a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424444/
https://www.ncbi.nlm.nih.gov/pubmed/28553462
http://dx.doi.org/10.1039/c4sc03279a

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