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From Tc(VII) to Tc(I); facile syntheses of bis-arene complexes [(99(m))Tc(arene)(2)](+) from pertechnetate

Bis-arene complexes of technetium represent a fundamental class of organometallic compounds. Due to complex synthetic routes, no detailed insights into their properties have been reported so far. Reacting [(99)TcO(4)](–) with arenes in the exclusive presence of AlCl(3) gives highly stable [(99)Tc(ar...

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Detalles Bibliográficos
Autores principales: Benz, Michael, Braband, Henrik, Schmutz, Paul, Halter, Jonathan, Alberto, Roger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424581/
https://www.ncbi.nlm.nih.gov/pubmed/28553465
http://dx.doi.org/10.1039/c4sc02461c