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From Tc(VII) to Tc(I); facile syntheses of bis-arene complexes [(99(m))Tc(arene)(2)](+) from pertechnetate
Bis-arene complexes of technetium represent a fundamental class of organometallic compounds. Due to complex synthetic routes, no detailed insights into their properties have been reported so far. Reacting [(99)TcO(4)](–) with arenes in the exclusive presence of AlCl(3) gives highly stable [(99)Tc(ar...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424581/ https://www.ncbi.nlm.nih.gov/pubmed/28553465 http://dx.doi.org/10.1039/c4sc02461c |