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Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding

Neptunium complexes in the formal oxidation states II, III, and IV supported by cyclopentadienyl ligands are explored, and significant differences between Np and U highlighted as a result. A series of neptunium(iii) cyclopentadienyl (Cp) complexes [Np(Cp)(3)], its bis-acetonitrile adduct [Np(Cp)(3)(...

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Detalles Bibliográficos
Autores principales: Dutkiewicz, Michał S., Apostolidis, Christos, Walter, Olaf, Arnold, Polly L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5431675/
https://www.ncbi.nlm.nih.gov/pubmed/28553487
http://dx.doi.org/10.1039/c7sc00034k