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Regulating signal enhancement with coordination-coupled deprotonation of a hydrazone switch

Proton relay plays an important role in many biocatalytic pathways. In order to mimic such processes in the context of molecular switches, we developed coordination-coupled deprotonation (CCD) driven signaling and signal enhancement sequences. This was accomplished by using the zinc(ii)-initiated CC...

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Detalles Bibliográficos
Autores principales: Foy, Justin T., Ray, Debdas, Aprahamian, Ivan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433045/
https://www.ncbi.nlm.nih.gov/pubmed/28553470
http://dx.doi.org/10.1039/c4sc02882a