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Reversible assembly of enantiomeric helical polymers: from fibers to gels

A novel class of stereocomplexes is described by the interaction of helically complementary poly(phenylacetylene)s (PPAs) carrying an α-methoxy-α-trifluoromethylphenylacetamide pendant group. The formation of the stereocomplex requires the presence of cis amide bonds on the external crest of the pol...

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Detalles Bibliográficos
Autores principales: Leiras, Seila, Freire, Félix, Quiñoá, Emilio, Riguera, Ricardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433055/
https://www.ncbi.nlm.nih.gov/pubmed/28553473
http://dx.doi.org/10.1039/c4sc02401j