Phosphazene-catalyzed desymmetrization of cyclohexadienones by dithiane addition

We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered dithiane nucleophile. Mild reaction conditions allow the formation of diversely functionalized fused bicyclic lactones. The products participate in facially selective additions from the convex surfac...

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Detalles Bibliográficos
Autores principales: Horwitz, Matthew A, Massolo, Elisabetta, Johnson, Jeffrey S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433211/
https://www.ncbi.nlm.nih.gov/pubmed/28546832
http://dx.doi.org/10.3762/bjoc.13.75

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433211/
https://www.ncbi.nlm.nih.gov/pubmed/28546832
http://dx.doi.org/10.3762/bjoc.13.75

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