Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles

A carbodiphosphorane ((Ph(3)P)(2)C) mediated synthesis of the first triflyloxyphosphonium dication (1(2+)) bearing two electrophilic sites is presented. Depending on the nucleophile, 1(2+) reacts selectively either at the sulfur atom of the triflyloxy moiety or at the directly attached phosphorus at...

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Detalles Bibliográficos
Autores principales: Yogendra, S., Hennersdorf, F., Bauzá, A., Frontera, A., Fischer, R., Weigand, J. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433424/
https://www.ncbi.nlm.nih.gov/pubmed/28229147
http://dx.doi.org/10.1039/c7cc00982h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433424/
https://www.ncbi.nlm.nih.gov/pubmed/28229147
http://dx.doi.org/10.1039/c7cc00982h

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