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Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles
A carbodiphosphorane ((Ph(3)P)(2)C) mediated synthesis of the first triflyloxyphosphonium dication (1(2+)) bearing two electrophilic sites is presented. Depending on the nucleophile, 1(2+) reacts selectively either at the sulfur atom of the triflyloxy moiety or at the directly attached phosphorus at...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433424/ https://www.ncbi.nlm.nih.gov/pubmed/28229147 http://dx.doi.org/10.1039/c7cc00982h |